prikaz prve stranice dokumenta Solvolysis rate of 3-methyl-2- (3-pentynyl) · 2-cyclohexenyl p-nitrobenzoate. A model system for n-participation of the CC triple bond
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Scientific paper - Original scientific paper
Solvolysis rate of 3-methyl-2- (3-pentynyl) · 2-cyclohexenyl p-nitrobenzoate. A model system for n-participation of the CC triple bond
Croatica Chemica Acta, 57 (1984), 3; 331-337. urn:nbn:hr:163:938462
Ladika, Mladen; Sunko, Dionis E.; Borčić, Stanko

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Ladika, M., Sunko, D. E. & Borčić, S. (1984). Solvolysis rate of 3-methyl-2- (3-pentynyl) · 2-cyclohexenyl p-nitrobenzoate. A model system for n-participation of the CC triple bond. Croatica Chemica Acta, 57. (3), 331-337. Retrieved from https://urn.nsk.hr/urn:nbn:hr:163:938462

Ladika, Mladen, et al. "Solvolysis rate of 3-methyl-2- (3-pentynyl) · 2-cyclohexenyl p-nitrobenzoate. A model system for n-participation of the CC triple bond." Croatica Chemica Acta, vol. 57, no. 3, 1984, pp. 331-337. https://urn.nsk.hr/urn:nbn:hr:163:938462

Ladika, Mladen, Dionis E. Sunko and Stanko Borčić. "Solvolysis rate of 3-methyl-2- (3-pentynyl) · 2-cyclohexenyl p-nitrobenzoate. A model system for n-participation of the CC triple bond." Croatica Chemica Acta 57, no. 3 (1984): 331-337. https://urn.nsk.hr/urn:nbn:hr:163:938462

Ladika, M., Sunko, D. E. and Borčić, S. (1984) 'Solvolysis rate of 3-methyl-2- (3-pentynyl) · 2-cyclohexenyl p-nitrobenzoate. A model system for n-participation of the CC triple bond', Croatica Chemica Acta, 57(3), pp. 331-337. Available at: https://urn.nsk.hr/urn:nbn:hr:163:938462 (Accessed 27 April 2024)

Ladika M, Sunko DE, Borčić S. Solvolysis rate of 3-methyl-2- (3-pentynyl) · 2-cyclohexenyl p-nitrobenzoate. A model system for n-participation of the CC triple bond. Croatica Chemica Acta [Internet]. 1984 [cited 2024 April 27];57(3):331-337. Available at: https://urn.nsk.hr/urn:nbn:hr:163:938462

M. Ladika, D. E. Sunko and S. Borčić, "Solvolysis rate of 3-methyl-2- (3-pentynyl) · 2-cyclohexenyl p-nitrobenzoate. A model system for n-participation of the CC triple bond", Croatica Chemica Acta, vol. 57, no. 3, pp. 331-337, 1984. [Online]. Available at: https://urn.nsk.hr/urn:nbn:hr:163:938462. [Accessed: 27 April 2024]

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Title (english)Solvolysis rate of 3-methyl-2- (3-pentynyl) · 2-cyclohexenyl p-nitrobenzoate. A model system for n-participation of the CC triple bond
AuthorMladen Ladika
AuthorDionis E. Sunko
AuthorStanko Borčić
Author's institutionUniversity of Zagreb
Faculty of Pharmacy and Biochemistry
(Department of organic chemistry)
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Organic Chemistry
Abstract (english)
The synthesis of 3-methyl-2-:(3-rpentynyl)-2-cycloheocenyl p-nitro1benzoa1te is desc["ibed. This ester so1lvolyzes in 97°/o CF3CH20H at 2'5 °C without n-participa:tion of the CC trLple bond, showing solvoiysis rate retardaition in comparison with the saturated anafog. This result is e~piained by electron-withdrawing inductiove e1ffect 01f 1the CC trirple bond. The lo.g k va~ues of alkanyl- (4), alikenyl- (5, 6), and alkyny:l-substitJu·ted (10) esters show good linear correia1tion With the pK. values of the cOirresrponding car:boxyJ'ic acids.
Languageenglish
Publication typeScientific paper - Original scientific paper
Publication statusPublished
Peer reviewPeer review - international
Publication versionPublished version
Journal titleCroatica Chemica Acta
Numberingvol. 57, no. 3, pp. 331-337
p-ISSN0011-1643
e-ISSN1334-417X
URN:NBNurn:nbn:hr:163:938462
Publication1984
Document URLhttps://hrcak.srce.hr/194149
Type of resourceText
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2020-04-30 14:54:47