Ferrocenylalkyl carbocations. II. Contribution to the problem of the structure of ferrocenylmethyl carhocation

Scientific paper - Preliminary note / Short communication

• Author: S. Ursić
• Author's institution: University of Zagreb; Faculty of Pharmacy and Biochemistry; (Department of physical chemistry)
• Scientific / art field, discipline and subdiscipline: NATURAL SCIENCES; Chemistry; Physical Chemistry

Abstract (english)

In this communication, an unusually large secondary a-deuterium kinetic
isotope effect for hydrolysis of the ferrocenylmethylquinolinium · ion, that
elucidates significantly the problem of the structure and manner in which
stabilisation of the a-ferrocenylalkyl carbocations occurs, will be reported. This
problem arises mainly from uncertainties as to whether some direct bonding
between iron and the cationic center is of significance in the stabilisation of
a-ferrocenylalkyl carbocations.

• Language: english
• Publication type: Scientific paper - Preliminary note / Short communication
• Publication status: Published
• Peer review: Peer review - international
• Publication version: Published version
• Journal title: Croatica Chemica Acta
• Numbering: vol. 55, no. 3, pp. 305-308
• p-ISSN: 0011-1643
• e-ISSN: 1334-417X
• URN:NBN: urn:nbn:hr:163:632526
• Publication: 1982
• Document URL: https://hrcak.srce.hr/194266
• Type of resource: Text
• Access conditions: Open access
• Created on: 2020-05-05 11:23:35