β-Methyl-D-glucofururonohydroxamic acid, the first sugar-hydroxamic acid and its iron(III) complexes in solution

Uršić, Stanko; Zorc, Branka; Pilepić, Viktor; Vikić-Topić, Dražen

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Scientific paper - Original scientific paper

β-Methyl-D-glucofururonohydroxamic acid, the first sugar-hydroxamic acid and its iron(III) complexes in solution

Croatica Chemica Acta, 65 (1992), 4; 851-857. urn:nbn:hr:163:186690

Uršić, Stanko; Zorc, Branka; Pilepić, Viktor; Vikić-Topić, Dražen

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APA 6th Edition

Uršić, S., Zorc, B., Pilepić, V. & Vikić Topić, D. (1992). β-Methyl-D-glucofururonohydroxamic acid, the first sugar-hydroxamic acid and its iron(III) complexes in solution. Croatica Chemica Acta, 65. (4), 851-857. Retrieved from https://urn.nsk.hr/urn:nbn:hr:163:186690

MLA 8th Edition

Uršić, Stanko, et al. "β-Methyl-D-glucofururonohydroxamic acid, the first sugar-hydroxamic acid and its iron(III) complexes in solution." Croatica Chemica Acta, vol. 65, no. 4, 1992, pp. 851-857. https://urn.nsk.hr/urn:nbn:hr:163:186690

Chicago 17th Edition

Uršić, Stanko, Branka Zorc, Viktor Pilepić and Dražen Vikić Topić. "β-Methyl-D-glucofururonohydroxamic acid, the first sugar-hydroxamic acid and its iron(III) complexes in solution." Croatica Chemica Acta 65, no. 4 (1992): 851-857. https://urn.nsk.hr/urn:nbn:hr:163:186690

Harvard

Uršić, S., et al. (1992) 'β-Methyl-D-glucofururonohydroxamic acid, the first sugar-hydroxamic acid and its iron(III) complexes in solution', Croatica Chemica Acta, 65(4), pp. 851-857. Available at: https://urn.nsk.hr/urn:nbn:hr:163:186690 (Accessed 04 December 2024)

Vancouver

Uršić S, Zorc B, Pilepić V, Vikić Topić D. β-Methyl-D-glucofururonohydroxamic acid, the first sugar-hydroxamic acid and its iron(III) complexes in solution. Croatica Chemica Acta [Internet]. 1992 [cited 2024 December 04];65(4):851-857. Available at: https://urn.nsk.hr/urn:nbn:hr:163:186690

IEEE

S. Uršić, B. Zorc, V. Pilepić and D. Vikić Topić, "β-Methyl-D-glucofururonohydroxamic acid, the first sugar-hydroxamic acid and its iron(III) complexes in solution", Croatica Chemica Acta, vol. 65, no. 4, pp. 851-857, 1992. [Online]. Available at: https://urn.nsk.hr/urn:nbn:hr:163:186690. [Accessed: 04 December 2024]

Cite this item: https://urn.nsk.hr/urn:nbn:hr:163:186690

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Title (english)	β-Methyl-D-glucofururonohydroxamic acid, the first sugar-hydroxamic acid and its iron(III) complexes in solution
Author	Stanko Uršić
Author	Branka Zorc
Author	Viktor Pilepić MBZ: 200682
Author	Dražen Vikić-Topić
Author's institution	University of Zagreb Faculty of Pharmacy and Biochemistry (Department of medicinal chemistry)
Author's institution	University of Zagreb Faculty of Pharmacy and Biochemistry (Department of physical chemistry)
Scientific / art field, discipline and subdiscipline	NATURAL SCIENCES Chemistry Physical Chemistry
Abstract (english)	/J-methyl-D-glucofururonohydroxamic acid sodium salt, the first sugar- hydroxamic acid was synthesized starting from y-lactone of /?-methyl-D- glucofururonoside and characterized by its physical properties and l3C NMR and IR spectral data. Investigation of the coordination ability of /J-methyl- D-glucofururonohydroxamic acid toward the iron(III) in solution reveals the existance of sequential complexation reactions, giving mono-, bis- and tris- (hydroxamato)iron(III) complexes. The equilibrium quotients Qn for the formation of iron(III) complexes with /J-methyl-D-glucofururonohydroxamic acid in solution and at ionic strength of 2.0 M (NaC104 or NaNOs) were determined. The equilibrium quotients Q„, defined as Qn = [FeLn]<3_n) + [H + ]n/[Fe3 + ] [HL]" are as follows: Q,, 34.59 (0.34); Q2, 206.20 (14.86) and Q3, 0.019 (0.007). The values of Amax and the molar absorption coefficient at Amax in visible spectra of mono- and trìs-/?-methyl-D-glucofururonohydro- xamato complexes are 495 nm and 1067(4) mol-1 dm3 cm-1 and 425 nm and 2680 moh1 dm3 cm-1, respectively. These figures are very similar to the corresponding values for the other aliphatic hydroxamate.
Language	english
Publication type	Scientific paper - Original scientific paper
Publication status	Published
Peer review	Peer review - international
Publication version	Published version
Journal title	Croatica Chemica Acta
Numbering	vol. 65, no. 4, pp. 851-857
p-ISSN	0011-1643
e-ISSN	1334-417X
URN:NBN	urn:nbn:hr:163:186690
Publication	1992
Document URL	https://hrcak.srce.hr/137143
Type of resource	Text
Access conditions	Open access
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Created on	2020-04-29 15:43:22