Kinetic study of the substitution of pyridine by cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D mechanism

Biruš, M.; Pribanić, M.

prikaz prve stranice dokumenta Kinetic study of the substitution of pyridine by cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D mechanism

Scientific paper - Preliminary note / Short communication

Kinetic study of the substitution of pyridine by cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D mechanism

Croatica Chemica Acta, 49 (1977), 1; 65-68. urn:nbn:hr:163:389119

Biruš, M.; Pribanić, M.

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APA 6th Edition

Biruš, M. & Pribanić, M. (1977). Kinetic study of the substitution of pyridine by cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D mechanism. Croatica Chemica Acta, 49. (1), 65-68. Retrieved from https://urn.nsk.hr/urn:nbn:hr:163:389119

MLA 8th Edition

Biruš, M. and M. Pribanić. "Kinetic study of the substitution of pyridine by cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D mechanism." Croatica Chemica Acta, vol. 49, no. 1, 1977, pp. 65-68. https://urn.nsk.hr/urn:nbn:hr:163:389119

Chicago 17th Edition

Biruš, M. and M. Pribanić. "Kinetic study of the substitution of pyridine by cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D mechanism." Croatica Chemica Acta 49, no. 1 (1977): 65-68. https://urn.nsk.hr/urn:nbn:hr:163:389119

Harvard

Biruš, M. and Pribanić, M. (1977) 'Kinetic study of the substitution of pyridine by cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D mechanism', Croatica Chemica Acta, 49(1), pp. 65-68. Available at: https://urn.nsk.hr/urn:nbn:hr:163:389119 (Accessed 14 November 2024)

Vancouver

Biruš M, Pribanić M. Kinetic study of the substitution of pyridine by cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D mechanism. Croatica Chemica Acta [Internet]. 1977 [cited 2024 November 14];49(1):65-68. Available at: https://urn.nsk.hr/urn:nbn:hr:163:389119

IEEE

M. Biruš and M. Pribanić, "Kinetic study of the substitution of pyridine by cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D mechanism", Croatica Chemica Acta, vol. 49, no. 1, pp. 65-68, 1977. [Online]. Available at: https://urn.nsk.hr/urn:nbn:hr:163:389119. [Accessed: 14 November 2024]

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Title (english)	Kinetic study of the substitution of pyridine by cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D mechanism
Author	M. Biruš
Author	M. Pribanić MBZ: 38805
Author's institution	University of Zagreb Faculty of Pharmacy and Biochemistry (Department of general and inorganic chemistry)
Scientific / art field, discipline and subdiscipline	NATURAL SCIENCES Chemistry
Abstract (english)	A kinetic study of the reaction between the cyanide ion and the bis(pyridine)cobalt(III)hematoporphyrin-IX complex to give (CN)2cobalt(lll)hematoporphyrin-IX has shown that the axial ligand substitution occurs by a purely dissociative (D but not la) mechanism in chloroform involving predissociation to a ' five-co- ordinate (pyridine)cobalt(lll)hematoporphyrin-IX complex.
Language	english
Publication type	Scientific paper - Preliminary note / Short communication
Publication status	Published
Peer review	Peer review - international
Publication version	Published version
Journal title	Croatica Chemica Acta
Numbering	vol. 49, no. 1, pp. 65-68
p-ISSN	0011-1643
e-ISSN	1334-417X
URN:NBN	urn:nbn:hr:163:389119
Publication	1977
Document URL	https://hrcak.srce.hr/196413
Type of resource	Text
Access conditions	Open access
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Created on	2020-05-05 15:18:31