prikaz prve stranice dokumenta Secondary deuterium isotope effects in some S N1 and E2 reactions
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Secondary deuterium isotope effects in some S N1 and E2 reactions
Croatica Chemica Acta, 34 (1962), 1; 7-12. urn:nbn:hr:163:358235
Ašperger, S.; Ilakovac, N.; Pavlović, D .

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Ašperger, S., Ilakovac, N. i Pavlović, D. .. (1962). Secondary deuterium isotope effects in some S N1 and E2 reactions. Croatica Chemica Acta, 34. (1), 7-12. Preuzeto s https://urn.nsk.hr/urn:nbn:hr:163:358235

Ašperger, S., et al. "Secondary deuterium isotope effects in some S N1 and E2 reactions." Croatica Chemica Acta, vol. 34, br. 1, 1962, str. 7-12. https://urn.nsk.hr/urn:nbn:hr:163:358235

Ašperger, S., N. Ilakovac i D . Pavlović. "Secondary deuterium isotope effects in some S N1 and E2 reactions." Croatica Chemica Acta 34, br. 1 (1962): 7-12. https://urn.nsk.hr/urn:nbn:hr:163:358235

Ašperger, S., Ilakovac, N. i Pavlović, D. .. (1962) 'Secondary deuterium isotope effects in some S N1 and E2 reactions', Croatica Chemica Acta, 34(1), str. 7-12. Preuzeto s: https://urn.nsk.hr/urn:nbn:hr:163:358235 (Datum pristupa: 20.04.2024.)

Ašperger S, Ilakovac N, Pavlović D.. Secondary deuterium isotope effects in some S N1 and E2 reactions. Croatica Chemica Acta [Internet]. 1962. [pristupljeno 20.04.2024.];34(1):7-12. Dostupno na: https://urn.nsk.hr/urn:nbn:hr:163:358235

S. Ašperger, N. Ilakovac i D. .. Pavlović, "Secondary deuterium isotope effects in some S N1 and E2 reactions", Croatica Chemica Acta, vol. 34, br. 1, str. 7-12, 1962. [Online]. Dostupno na: https://urn.nsk.hr/urn:nbn:hr:163:358235. [Citirano: 20.04.2024.]

Za citiranje koristite ovu mrežnu adresu: https://urn.nsk.hr/urn:nbn:hr:163:358235
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Podaci o radu
Naslov (engleski)Secondary deuterium isotope effects in some S N1 and E2 reactions
AutorS. Ašperger
AutorN. Ilakovac
AutorD . Pavlović
Autorova ustanovaSveučilište u Zagrebu
Farmaceutsko-biokemijski fakultet
Znanstveno / umjetničko
područje, polje i grana		PRIRODNE ZNANOSTI
Kemija
Sažetak (engleski)
An a-deuterium isotope effect kH/kn of 170/o was found in the E 2 reaction of 2-phenylethyl-l,l-d2 bromide with sodium ethoxide in ethanol. This supports the Streitwieser change-of-hybridization theory and the associated explanation of the absence of such effects in S N2 reactions as being due to the proximity of the incoming group. The magnitude of the ~- and a-deuterium isotope effects in the SNl and E2 reactions of some alkylsulphonium salts were determined and compared with the isotope effects of the corresponding alkyl-halides. An explanation for these differences is given.
Jezikengleski
Vrsta publikacijeZnanstveni rad - Izvorni znanstveni rad
Status objaveObjavljen
Vrsta recenzijeRecenziran - međunarodna recenzija
Verzija publikacijeObjavljena verzija rada (izdavačev PDF)
Naslov časopisaCroatica Chemica Acta
Brojčani podacivol. 34, br. 1, str. 7-12
p-ISSN0011-1643
e-ISSN1334-417X
URN:NBNurn:nbn:hr:163:358235
Datum objave publikacije1962
URL dokumentahttps://hrcak.srce.hr/208414
Vrsta resursaTekst
Prava pristupaOtvoreni pristup
Uvjeti korištenjaIkona licence Zaštićeno autorskim pravom.
Datum i vrijeme pohrane2020-05-11 14:38:18