prikaz prve stranice dokumenta Reactivity of some tertiary chlorides with methoxy and olefinic neighboring group
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Reactivity of some tertiary chlorides with methoxy and olefinic neighboring group
Croatica Chemica Acta, 69 (1996), 2; 563-568. urn:nbn:hr:163:609852
Borčić, Stanko; Kronja, Olga; Humski, Krešimir; Miletić, Sandra

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Borčić, S., Kronja, O., Humski, K. i Miletić, S. (1996). Reactivity of some tertiary chlorides with methoxy and olefinic neighboring group. Croatica Chemica Acta, 69. (2), 563-568. Preuzeto s https://urn.nsk.hr/urn:nbn:hr:163:609852

Borčić, Stanko, et al. "Reactivity of some tertiary chlorides with methoxy and olefinic neighboring group." Croatica Chemica Acta, vol. 69, br. 2, 1996, str. 563-568. https://urn.nsk.hr/urn:nbn:hr:163:609852

Borčić, Stanko, Olga Kronja, Krešimir Humski i Sandra Miletić. "Reactivity of some tertiary chlorides with methoxy and olefinic neighboring group." Croatica Chemica Acta 69, br. 2 (1996): 563-568. https://urn.nsk.hr/urn:nbn:hr:163:609852

Borčić, S., et al. (1996) 'Reactivity of some tertiary chlorides with methoxy and olefinic neighboring group', Croatica Chemica Acta, 69(2), str. 563-568. Preuzeto s: https://urn.nsk.hr/urn:nbn:hr:163:609852 (Datum pristupa: 12.11.2024.)

Borčić S, Kronja O, Humski K, Miletić S. Reactivity of some tertiary chlorides with methoxy and olefinic neighboring group. Croatica Chemica Acta [Internet]. 1996. [pristupljeno 12.11.2024.];69(2):563-568. Dostupno na: https://urn.nsk.hr/urn:nbn:hr:163:609852

S. Borčić, O. Kronja, K. Humski i S. Miletić, "Reactivity of some tertiary chlorides with methoxy and olefinic neighboring group", Croatica Chemica Acta, vol. 69, br. 2, str. 563-568, 1996. [Online]. Dostupno na: https://urn.nsk.hr/urn:nbn:hr:163:609852. [Citirano: 12.11.2024.]

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Podaci o radu
Naslov (engleski)Reactivity of some tertiary chlorides with methoxy and olefinic neighboring group
AutorStanko Borčić
AutorOlga Kronja
AutorKrešimir Humski
AutorSandra Miletić
Autorova ustanovaSveučilište u Zagrebu
Farmaceutsko-biokemijski fakultet
(Zavod za organsku kemiju)
Znanstveno / umjetničko
područje, polje i grana		PRIRODNE ZNANOSTI
Kemija
Organska kemija
Sažetak (engleski)
Solvolysis rates of tertiary chlorides 1-6 and their hexadeuterated analogs 1-dg-6-đe were measured in ethanol (q> = 80%) and 2,2,2- trifluoroethanol (w = 97%). The (5-deuterium KIE calculated showed that chloride 1 solvolyzes with n-participation of the methoxy group in the rate determining step, while chloride 2 solvolyzes mainly by way of a kc process. Based on the reduced P-deuterium isotope effect, it was also concluded that in the solvolysis of chloride 5 7t-electrons take part in the rate-determining step.
Jezikengleski
Vrsta publikacijeZnanstveni rad - Prethodno/kratko priopćenje
Status objaveObjavljen
Vrsta recenzijeRecenziran - međunarodna recenzija
Verzija publikacijeObjavljena verzija rada (izdavačev PDF)
Naslov časopisaCroatica Chemica Acta
Brojčani podacivol. 69, br. 2, str. 563-568
p-ISSN0011-1643
e-ISSN1334-417X
URN:NBNurn:nbn:hr:163:609852
Datum objave publikacije1996
URL dokumentahttps://hrcak.srce.hr/136672
Vrsta resursaTekst
Prava pristupaOtvoreni pristup
Uvjeti korištenjaIkona licence Zaštićeno autorskim pravom.
Datum i vrijeme pohrane2020-04-29 14:15:47