prikaz prve stranice dokumenta Nucleofugality of leaving groups
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Nucleofugality of leaving groups
Croatica Chemica Acta, 90 (2017), 4; 571-581. https://doi.org/10.5562/cca3283
Matić, Mirela; Denegri, Bernard; Jurić, Sandra; Kronja, Olga

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Matić, M., Denegri, B., Jurić, S. i Kronja, O. (2017). Nucleofugality of leaving groups. Croatica Chemica Acta, 90. (4), 571-581. doi: 10.5562/cca3283

Matić, Mirela, et al. "Nucleofugality of leaving groups." Croatica Chemica Acta, vol. 90, br. 4, 2017, str. 571-581. https://doi.org/10.5562/cca3283

Matić, Mirela, Bernard Denegri, Sandra Jurić i Olga Kronja. "Nucleofugality of leaving groups." Croatica Chemica Acta 90, br. 4 (2017): 571-581. https://doi.org/10.5562/cca3283

Matić, M., et al. (2017) 'Nucleofugality of leaving groups', Croatica Chemica Acta, 90(4), str. 571-581. doi: 10.5562/cca3283

Matić M, Denegri B, Jurić S, Kronja O. Nucleofugality of leaving groups. Croatica Chemica Acta [Internet]. 2017. [pristupljeno 15.11.2024.];90(4):571-581. doi: 10.5562/cca3283

M. Matić, B. Denegri, S. Jurić i O. Kronja, "Nucleofugality of leaving groups", Croatica Chemica Acta, vol. 90, br. 4, str. 571-581, 2017. [Online]. Dostupno na: https://urn.nsk.hr/urn:nbn:hr:163:396284. [Citirano: 15.11.2024.]

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Podaci o radu
Naslov (engleski)Nucleofugality of leaving groups
AutorMirela Matić
AutorBernard Denegri
AutorSandra Jurić
AutorOlga Kronja
Autorova ustanovaSveučilište u Zagrebu
Farmaceutsko-biokemijski fakultet
(Zavod za organsku kemiju)
Znanstveno / umjetničko
područje, polje i grana		PRIRODNE ZNANOSTI
Kemija
Organska kemija
Sažetak (engleski)
In this short authors' review, a method for determining experimental and calculated nucleofugalities of leaving groups in a given solvents according to LFER equation log k = sf (Nf + Ef) is presented. Also, a comprehensive overview of the experimental and calculated nucleofuges specific parameters (Nf and sf) for various negatively charged and neutral leaving groups is shown. Some applications of the above method have been demonstrated: use of the electrofugalitiy and nucleofugality scales to estimate the reactivities of a variety of substrates in various solvents, as well as assessment whether a given substrate is stable in a given solvent for a sufficent amount of time, which may indicate if the substrate can be handled in the solvent of choice during synthetic and other procedures. The method can also be used to establish whether the relative reactivity of leaving groups depends on the electrofuge moiety of the substrate. <br><a rel="license" href="http://creativecommons.org/licenses/by/4.0/"><img alt="Creative Commons License" style="border-width:0" src="https://i.creativecommons.org/l/by/4.0/80x15.png" /></a> This work is licensed under a <a rel="license" href="http://creativecommons.org/licenses/by/4.0/">Creative Commons Attribution 4.0 International License</a>.
Ključne riječi (engleski)
Jezikengleski
Vrsta publikacijeZnanstveni rad - Pregledni rad
Status objaveObjavljen
Vrsta recenzijeRecenziran - međunarodna recenzija
Verzija publikacijeObjavljena verzija rada (izdavačev PDF)
Naslov časopisaCroatica Chemica Acta
Brojčani podacivol. 90, br. 4, str. 571-581
p-ISSN0011-1643
e-ISSN1334-417X
DOIhttps://doi.org/10.5562/cca3283
URN:NBNurn:nbn:hr:163:396284
Datum objave publikacije2017
URL dokumentahttps://hrcak.srce.hr/198666
Vrsta resursaTekst
Prava pristupaOtvoreni pristup
Uvjeti korištenjaIkona licence Zaštićeno autorskim pravom.
Datum i vrijeme pohrane2020-04-14 16:50:45